Synthesis of anionic methylpalladium complexes with phosphine-sulfonate ligands and their activities for olefin polymerization.
نویسندگان
چکیده
Reaction of diarylphosphinobenzene-2-sulfonic acids with tertially amines, followed by addition of [PdMeCl(cod)], provided anionic methylpalladium(II) complexes with bidentate phosphine-sulfonate ligands, which show high activity for copolymerization of ethylene with methyl acrylate.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 1 شماره
صفحات -
تاریخ انتشار 2006